CBSE Physics Class XII — Step-by-step derivations for board examination
Chapter 1 — Electric Charges and Fields
1. Electric Field on the Axial Line of an Electric Dipole
3 MarksEvery Year
Given / Setup
An electric dipole consists of two equal and opposite charges $+q$ and $-q$ separated by distance $2a$. The dipole moment is $\vec{p} = q \cdot 2a$, directed from $-q$ to $+q$. Find the electric field at a point P on the axial line at distance $r$ from the centre of the dipole $(r \gg a)$.
Diagram: Place $-q$ at point A and $+q$ at point B on a horizontal line. O is the midpoint. P is a point on the axial line to the right of B, at distance $r$ from O. So AP $= r + a$ and BP $= r - a$.
Electric field at P due to $+q$ (along the direction away from $+q$, i.e., towards the right):
Final Result
$$\boxed{E_{\text{axial}} = \frac{1}{4\pi\varepsilon_0} \cdot \frac{2p}{r^3}}$$
Direction: along the dipole moment $\vec{p}$ (from $-q$ to $+q$)
Examiner Tip: Always draw the diagram showing the position of charges and point P. State clearly that $r \gg a$ before simplifying. Mention the direction of the net field. Write SI units of electric field: $\text{N/C}$ or $\text{V/m}$.
2. Electric Field on the Equatorial Line of an Electric Dipole
3 MarksEvery Year
Given / Setup
Same electric dipole: charges $+q$ and $-q$ separated by $2a$, dipole moment $p = q \cdot 2a$. Find the electric field at point P on the equatorial line (perpendicular bisector) at distance $r$ from the centre O.
Diagram: Dipole along horizontal axis with $-q$ at A and $+q$ at B. O is the centre. P is directly above O at distance $r$. The distances AP $=$ BP $= \sqrt{r^2 + a^2}$.
The magnitudes of electric fields at P due to $+q$ and $-q$ are equal (since both charges are equidistant from P):
The fields $E_1$ and $E_2$ are directed away from $+q$ and towards $-q$ respectively. Resolve each into components along the axial and equatorial directions. The components perpendicular to the dipole axis (vertical components) cancel out by symmetry.
The components parallel to the dipole axis add up. Each contributes $E_1 \cos\theta$, where $\cos\theta = \frac{a}{\sqrt{r^2 + a^2}}$. The net field is directed opposite to $\vec{p}$:
Final Result
$$\boxed{E_{\text{equatorial}} = \frac{1}{4\pi\varepsilon_0} \cdot \frac{p}{r^3}}$$
Direction: opposite to the dipole moment $\vec{p}$ (from $+q$ to $-q$)
Examiner Tip: Draw the diagram and clearly show vector resolution of $E_1$ and $E_2$. State that vertical components cancel. Mention direction is anti-parallel to $\vec{p}$. Note: $E_{\text{axial}} = 2 \times E_{\text{equatorial}}$ — examiners appreciate this comparison.
3. Torque on a Dipole in a Uniform Electric Field
3 MarksVery Frequent
Given / Setup
An electric dipole with dipole moment $\vec{p}$ is placed in a uniform electric field $\vec{E}$, making an angle $\theta$ with the field. Derive the expression for the torque experienced by the dipole.
Diagram: Show dipole AB (with $-q$ at A and $+q$ at B) of length $2a$ making angle $\theta$ with horizontal field $\vec{E}$. Forces $q\vec{E}$ and $-q\vec{E}$ act on the charges.
Force on charge $+q$: $\vec{F_1} = q\vec{E}$ (along $\vec{E}$). Force on charge $-q$: $\vec{F_2} = -q\vec{E}$ (opposite to $\vec{E}$).
Net force = $\vec{F_1} + \vec{F_2} = q\vec{E} - q\vec{E} = 0$. So the dipole does not undergo translational motion, but experiences a torque (couple).
The magnitude of the torque = force $\times$ perpendicular distance between the two forces. The perpendicular distance is $2a\sin\theta$:
$$\tau = qE \times 2a\sin\theta = (q \cdot 2a) \cdot E \sin\theta = pE\sin\theta$$
In vector form, using the cross product:
$$\vec{\tau} = \vec{p} \times \vec{E}$$
Final Result
$$\boxed{\tau = pE\sin\theta \quad \text{or} \quad \vec{\tau} = \vec{p} \times \vec{E}}$$
Torque is maximum when $\theta = 90°$ and zero when $\theta = 0°$ or $180°$.
Examiner Tip: Always mention that net force is zero (this earns a mark). Write both scalar and vector forms. State the conditions for maximum and zero torque. Draw a clear diagram showing the angle $\theta$.
4. Gauss’s Law: Electric Field due to an Infinite Plane Sheet of Charge
3 MarksEvery Year
Given / Setup
An infinite thin plane sheet has uniform surface charge density $\sigma$ (charge per unit area). Using Gauss’s law, find the electric field at a point near the sheet.
Diagram: Show the infinite plane sheet. Choose a cylindrical Gaussian surface (pill-box) with its axis perpendicular to the sheet, with one flat face on each side of the sheet. Let the cross-sectional area of each face be $A$.
Gauss’s Law states: $\oint \vec{E} \cdot d\vec{A} = \frac{q_{\text{enclosed}}}{\varepsilon_0}$
By symmetry, the electric field $\vec{E}$ is perpendicular to the sheet and points away from it on both sides (for positive $\sigma$). The magnitude is the same on both sides at equal distances.
For the cylindrical Gaussian surface, the flux through the curved surface is zero (since $\vec{E} \perp d\vec{A}$ on the curved surface, making $\vec{E} \cdot d\vec{A} = 0$).
The total flux is only through the two flat faces:
$$\oint \vec{E} \cdot d\vec{A} = EA + EA = 2EA$$
The charge enclosed by the Gaussian surface is $q_{\text{enclosed}} = \sigma A$. Applying Gauss’s Law:
$$2EA = \frac{\sigma A}{\varepsilon_0} \quad \Rightarrow \quad E = \frac{\sigma}{2\varepsilon_0}$$
Final Result
$$\boxed{E = \frac{\sigma}{2\varepsilon_0}}$$
The field is uniform (independent of distance from the sheet) and directed normally outward on both sides.
Examiner Tip: Draw the Gaussian surface clearly. State Gauss’s Law before applying it. Explain why the flux through the curved surface is zero. Mention that the field is independent of distance — this is a key result examiners look for.
Chapter 4 — Moving Charges and Magnetism
5. Magnetic Field on the Axis of a Circular Current Loop
3 MarksEvery Year
Given / Setup
A circular loop of radius $R$ carries a steady current $I$. Find the magnetic field at a point P on the axis of the loop at a distance $x$ from the centre, using the Biot-Savart law.
Diagram: Circular loop in the YZ-plane with centre O. Point P is on the X-axis at distance $x$ from O. A small current element $d\vec{l}$ is at the top of the loop. The distance from $d\vec{l}$ to P is $r = \sqrt{R^2 + x^2}$.
By Biot-Savart law, the magnetic field due to a small element $d\vec{l}$ at point P is:
Since $d\vec{l} \perp \vec{r}$ always (the element is tangent to the loop and $\vec{r}$ points from the element to P), we have $|d\vec{l} \times \hat{r}| = dl$.
The magnitude of the field due to each element is:
Resolve $d\vec{B}$ into components: one along the axis and one perpendicular to it. By symmetry, the perpendicular components from diametrically opposite elements cancel out. Only the axial components survive.
$$dB_{\text{axial}} = dB \cos\alpha = dB \cdot \frac{R}{\sqrt{R^2 + x^2}}$$
Integrate over the entire loop ($\oint dl = 2\pi R$):
Special case: At the centre of the loop ($x = 0$): $B = \frac{\mu_0 I}{2R}$
Final Result
$$\boxed{B = \frac{\mu_0 I R^2}{2(R^2 + x^2)^{3/2}}}$$
Direction: along the axis, given by the right-hand thumb rule.
Examiner Tip: State Biot-Savart law first. Draw the diagram showing the element, point P, and the angle. Explain clearly why perpendicular components cancel. The special case $B_{\text{centre}} = \mu_0 I / 2R$ is very frequently asked — always write it.
6. Force Between Two Parallel Current-Carrying Conductors
3 MarksVery Frequent
Given / Setup
Two long, straight, parallel conductors carry currents $I_1$ and $I_2$ and are separated by distance $d$. Find the force per unit length between them.
Diagram: Two vertical parallel wires separated by distance $d$. Wire 1 carries current $I_1$ upward, wire 2 carries current $I_2$ upward. Show the magnetic field due to wire 1 at the location of wire 2.
The magnetic field produced by conductor 1 at the location of conductor 2 (at distance $d$) is given by Ampere’s circuital law:
$$B_1 = \frac{\mu_0 I_1}{2\pi d}$$
Conductor 2, carrying current $I_2$, is placed in this field $B_1$. The force on a length $L$ of conductor 2 is:
Nature of force: Using Fleming’s left-hand rule, if currents are in the same direction, the force is attractive. If currents are in opposite directions, the force is repulsive.
Definition of Ampere: When $I_1 = I_2 = 1\text{ A}$ and $d = 1\text{ m}$, the force per unit length is $F/L = 2 \times 10^{-7}\text{ N/m}$.
Final Result
$$\boxed{\frac{F}{L} = \frac{\mu_0 I_1 I_2}{2\pi d}}$$
Attractive for parallel currents, repulsive for anti-parallel currents.
Examiner Tip: Always mention the definition of the ampere — it is a standard follow-up question. State whether the force is attractive or repulsive with reasoning. Draw the diagram showing field direction using the right-hand rule.
Chapter 6 — Electromagnetic Induction
7. Self-Inductance of a Solenoid
3 MarksVery Frequent
Given / Setup
A long solenoid of length $l$, cross-sectional area $A$, and total number of turns $N$ carries a current $I$. Derive the expression for its self-inductance $L$. Let $n = N/l$ be the number of turns per unit length.
Diagram: A long solenoid with uniformly wound turns. Show the uniform magnetic field $\vec{B}$ inside the solenoid, directed along the axis.
The magnetic field inside a long solenoid is uniform and given by:
$$B = \mu_0 n I = \mu_0 \frac{N}{l} I$$
The magnetic flux through each turn of the solenoid is:
$$\phi = B \cdot A = \mu_0 \frac{N}{l} I \cdot A$$
The total flux linkage with the solenoid (all $N$ turns) is:
$$N\phi = N \cdot \mu_0 \frac{N}{l} I A = \frac{\mu_0 N^2 A I}{l}$$
By definition, self-inductance $L$ is given by $N\phi = LI$. Therefore:
Final Result
$$\boxed{L = \mu_0 n^2 A l = \frac{\mu_0 N^2 A}{l}}$$
SI unit of self-inductance: henry (H)
Examiner Tip: Write the formula for the magnetic field inside the solenoid as the first step. Define the flux linkage clearly (total flux = $N \times$ flux through one turn). State the SI unit of inductance. If asked about factors, mention $L$ depends on $n^2$, $A$, and $l$ but not on current $I$.
Chapter 7 — Alternating Current
13. Impedance of a Series LCR Circuit
5 MarksEvery Year
Given / Setup
A resistor $R$, inductor $L$, and capacitor $C$ are connected in series with an AC source of EMF $V = V_0 \sin\omega t$. Derive the expression for the impedance of the circuit using the phasor diagram method.
Diagram (Phasor): Take current $I$ as the reference phasor (horizontal). $V_R$ is along $I$ (in phase). $V_L$ leads $I$ by $90°$ (upward). $V_C$ lags $I$ by $90°$ (downward). The net voltage $V$ is the vector sum.
Let the current in the circuit be $I = I_0 \sin(\omega t)$ (same current flows through all elements in series).
The voltage across each element:
Across $R$: $V_R = IR$ (in phase with $I$)
Across $L$: $V_L = IX_L = I\omega L$ (leads $I$ by $90°$)
Across $C$: $V_C = IX_C = \frac{I}{\omega C}$ (lags $I$ by $90°$)
In the phasor diagram, $V_L$ and $V_C$ are opposite in direction. Their resultant is $(V_L - V_C)$ directed upward (assuming $V_L > V_C$). This resultant is perpendicular to $V_R$.
By Pythagoras’ theorem, the amplitude of the resultant voltage is:
If $X_L > X_C$: circuit is inductive, voltage leads current. If $X_L < X_C$: circuit is capacitive, current leads voltage.
Final Result
$$\boxed{Z = \sqrt{R^2 + \left(\omega L - \frac{1}{\omega C}\right)^2}}$$
$$\boxed{\tan\phi = \frac{\omega L - \frac{1}{\omega C}}{R}}$$
Examiner Tip: The phasor diagram is essential — draw it neatly. Label all four phasors ($V_R$, $V_L$, $V_C$, and the resultant $V$). State which quantity leads/lags. Write the expressions for $X_L$ and $X_C$ before substituting. Mention the phase angle and discuss all three cases (inductive, capacitive, resonance).
14. Condition for Resonance in a Series LCR Circuit
5 MarksVery Frequent
Given / Setup
In a series LCR circuit connected to an AC source, derive the condition for resonance and the resonant frequency. Also discuss the properties of the circuit at resonance.
From the impedance expression derived above:
$$Z = \sqrt{R^2 + \left(\omega L - \frac{1}{\omega C}\right)^2}$$
The current amplitude is $I_0 = V_0 / Z$. Current is maximum when impedance $Z$ is minimum.
$Z$ is minimum when the reactive part vanishes, i.e., when:
$$\omega L - \frac{1}{\omega C} = 0 \quad \Rightarrow \quad \omega L = \frac{1}{\omega C}$$
Solving for the resonant angular frequency $\omega_0$:
Phase angle $\phi = 0$ — voltage and current are in phase
$V_L = V_C$ (they cancel each other)
The circuit behaves as a purely resistive circuit
Power factor $\cos\phi = 1$ (maximum power is dissipated)
Final Result
$$\boxed{f_0 = \frac{1}{2\pi\sqrt{LC}}}$$
At resonance: $Z = R$, $\phi = 0$, current is maximum.
Examiner Tip: Clearly state the condition $X_L = X_C$ and derive the frequency from it. List all properties at resonance — examiners give marks for each point. If asked to draw a graph, sketch $I$ vs. $\omega$ showing the sharp peak at $\omega_0$, and show that the peak is sharper for smaller $R$.
15. Principle of Working of a Transformer
5 MarksVery Frequent
Given / Setup
A transformer consists of two coils — primary (with $N_p$ turns) and secondary (with $N_s$ turns) — wound on the same soft iron core. An alternating voltage $V_p$ is applied to the primary coil. Derive the relation between voltages and turns, and between currents, assuming an ideal transformer.
Diagram: Two coils wound on a laminated soft iron core (closed loop core). Primary coil on the left connected to AC source. Secondary coil on the right connected to a load.
When an alternating voltage $V_p$ is applied to the primary coil, it produces an alternating current which creates a time-varying magnetic flux $\phi$ in the core.
Since the core channels all the flux, the same flux $\phi$ links both coils. By Faraday’s law of electromagnetic induction, the induced EMF in the primary is:
$$\varepsilon_p = -N_p \frac{d\phi}{dt}$$
Similarly, the induced EMF in the secondary is:
$$\varepsilon_s = -N_s \frac{d\phi}{dt}$$
Dividing the two equations (and noting that for an ideal transformer, $\varepsilon_p \approx V_p$ and $\varepsilon_s \approx V_s$):
$$\frac{V_s}{V_p} = \frac{N_s}{N_p} = k \quad \text{(turns ratio)}$$
If $k > 1$: step-up transformer ($V_s > V_p$). If $k < 1$: step-down transformer ($V_s < V_p$).
For an ideal transformer, there are no energy losses. By conservation of energy, input power = output power:
A step-up transformer increases voltage but decreases current proportionally, and vice versa.
Energy losses in a real transformer:
Copper losses: $I^2R$ heating in the windings (reduced by using thick copper wire)
Eddy current losses: Induced currents in the core (reduced by using laminated core)
Hysteresis loss: Energy spent in repeated magnetisation (reduced by using soft iron core)
Flux leakage: Not all flux links both coils (reduced by winding coils over each other)
Final Result
$$\boxed{\frac{V_s}{V_p} = \frac{N_s}{N_p}} \qquad \boxed{\frac{I_s}{I_p} = \frac{N_p}{N_s}}$$
For an ideal transformer: $V_p I_p = V_s I_s$ (power is conserved)
Examiner Tip: State Faraday’s law explicitly. Mention the assumption of zero flux leakage for ideal transformer. List all four sources of energy losses with how to minimise each — this is almost always asked as a follow-up. Draw a labelled diagram of the transformer.
Chapter 9 — Ray Optics
10. Refraction at a Single Spherical Surface
5 MarksVery Frequent
Given / Setup
A spherical refracting surface of radius of curvature $R$ separates two media of refractive indices $n_1$ and $n_2$ ($n_2 > n_1$). An object is placed in medium 1. Derive the relation between object distance $u$, image distance $v$, and the radius of curvature $R$.
Diagram: Convex spherical surface with centre of curvature C and pole P. Object O is in medium 1 (left). A ray from O hits the surface at M, making angle of incidence $i$ with the normal MC. The refracted ray forms image I in medium 2 (right).
Sign convention: All distances measured from P. Distances along the direction of light are positive.
For a ray from O incident at point M on the surface, let the angles made with the principal axis by OM, MI, and MC be $\alpha$, $\beta$, and $\gamma$ respectively. The angle of incidence is $i$ and angle of refraction is $r$.
From the geometry of the triangle OMC: the exterior angle $i = \alpha + \gamma$.
From triangle MCI: the exterior angle $\gamma = r + \beta$, so $r = \gamma - \beta$.
For small angles (paraxial ray approximation): $\sin i \approx i$ and $\sin r \approx r$. Applying Snell’s law: $n_1 \sin i = n_2 \sin r$:
Final Result
$$\boxed{\frac{n_2}{v} - \frac{n_1}{u} = \frac{n_2 - n_1}{R}}$$
Examiner Tip: State the sign convention explicitly before starting. Draw a clear diagram showing O, P, C, M, I, and the normal. State the paraxial ray approximation ($\sin\theta \approx \theta$). Show the geometry to get the angle relations carefully — this is where most students lose marks.
9. Lens Maker’s Formula
5 MarksEvery Year
Given / Setup
A thin convex lens of refractive index $n_2$ (or $\mu$) is placed in a medium of refractive index $n_1$ (usually air, $n_1 = 1$). The lens has two spherical surfaces with radii of curvature $R_1$ and $R_2$. Derive the lens maker’s formula using refraction at each surface.
Diagram: A thin biconvex lens with surfaces $S_1$ (radius $R_1$) and $S_2$ (radius $R_2$). Object O is in front of $S_1$. First refraction at $S_1$ produces an intermediate image $I'$ inside the lens. $I'$ acts as a virtual object for refraction at $S_2$, producing the final image $I$.
Refraction at surface $S_1$: Light goes from medium of refractive index $n_1$ to $n_2$. Object distance is $u$ and the intermediate image is at distance $v'$. Using the result for refraction at a single spherical surface:
Refraction at surface $S_2$: Light goes from medium $n_2$ to $n_1$. The intermediate image $I'$ at distance $v'$ from $S_1$ acts as the object for $S_2$. For a thin lens, we take the object distance for $S_2$ as $v'$ itself. The final image is at distance $v$:
When the object is at infinity ($u \to \infty$), the image is formed at the focal point ($v = f$). Setting $\frac{1}{u} = 0$ and writing $\mu = n_2/n_1$:
Final Result
$$\boxed{\frac{1}{f} = (\mu - 1)\left(\frac{1}{R_1} - \frac{1}{R_2}\right)}$$
This is the Lens Maker’s Formula. It also gives the thin lens formula: $\frac{1}{v} - \frac{1}{u} = \frac{1}{f}$.
Examiner Tip: Derive refraction at a single spherical surface first if asked (this is often the full 5-mark question). Clearly show how the intermediate image of the first surface becomes the object for the second surface. State the thin lens assumption. Write the thin lens equation as a consequence. This derivation is the single most frequently asked 5-mark derivation.
Chapter 10 — Wave Optics
11. Fringe Width in Young’s Double Slit Experiment
5 MarksEvery Year
Given / Setup
In Young’s double slit experiment, two coherent sources $S_1$ and $S_2$ are separated by a distance $d$. A screen is placed at a distance $D$ from the slits ($D \gg d$). Derive the expression for fringe width $\beta$ and the conditions for constructive and destructive interference.
Diagram: Two narrow slits $S_1$ and $S_2$ separated by $d$, with a screen at distance $D$. A point P on the screen is at distance $y$ from the central point O. Show the path difference $S_2P - S_1P$.
Let point P on the screen be at distance $y$ from the central point O (the perpendicular bisector of $S_1S_2$).
The fringe width is the same for both bright and dark fringes and is independent of $n$ (i.e., all fringes are equally spaced).
Final Result
$$\boxed{\beta = \frac{\lambda D}{d}}$$
Fringe width is directly proportional to $\lambda$ and $D$, and inversely proportional to $d$.
Examiner Tip: Draw a clear diagram with all labels ($S_1$, $S_2$, P, O, $D$, $d$, $y$). Derive the path difference step carefully. Write conditions for both bright and dark fringes. State that fringe width is the same for both. If asked what happens when the experiment is performed in water, state that $\lambda$ decreases, so fringe width decreases.
Chapter 11 — Dual Nature of Radiation and Matter
8. Einstein’s Photoelectric Equation
3 MarksVery Frequent
Given / Setup
When light of frequency $\nu$ falls on a metal surface, photoelectrons are emitted. Einstein extended Planck’s quantum theory to explain the photoelectric effect. Derive the photoelectric equation.
Key assumptions:
Light consists of discrete packets of energy called photons, each with energy $E = h\nu$.
In the photoelectric effect, one photon is completely absorbed by one electron.
The minimum energy required to free an electron from the metal surface is the work function $W_0$ (or $\phi$).
A photon of frequency $\nu$ has energy:
$$E = h\nu$$
When this photon strikes the metal surface, part of its energy is used to overcome the work function $W_0$ (the minimum energy needed to release the electron from the metal):
$$W_0 = h\nu_0$$
where $\nu_0$ is the threshold frequency (minimum frequency below which no photoelectric emission occurs).
The remaining energy appears as kinetic energy of the emitted electron. By conservation of energy:
$$h\nu = W_0 + KE_{\max}$$
where $KE_{\max} = \frac{1}{2}mv_{\max}^2$ is the maximum kinetic energy of the emitted photoelectron.
Since $KE_{\max} = eV_0$ (where $V_0$ is the stopping potential), we can also write:
Final Result
$$\boxed{h\nu = W_0 + KE_{\max} = h\nu_0 + \frac{1}{2}mv_{\max}^2}$$
This equation explains all observed features of the photoelectric effect.
Examiner Tip: State the three key assumptions (photon nature, one-to-one interaction, threshold energy). Explain what happens when $\nu < \nu_0$ (no emission regardless of intensity). Mention that this equation explains all three experimental laws: (1) existence of threshold frequency, (2) KE depends on frequency not intensity, (3) instantaneous emission. Write both forms of the equation ($h\nu = W_0 + KE_{\max}$ and $eV_0 = h\nu - h\nu_0$).
Chapter 12 — Atoms
12. Bohr’s Theory of Hydrogen Atom
5 MarksEvery Year
Given / Setup
Bohr’s model of the hydrogen atom: an electron of mass $m$ and charge $e$ revolves around a nucleus of charge $+e$ in a circular orbit of radius $r$. The model is based on three postulates:
Postulate 1: The electron revolves in certain stable orbits without radiating energy.
Postulate 2 (Quantisation): The angular momentum of the electron in a permitted orbit is an integral multiple of $\hbar = h/2\pi$: $mvr = n\hbar$.
Postulate 3: When an electron transitions between orbits, it emits or absorbs a photon of energy $h\nu = E_i - E_f$.
Derive expressions for the radius $r_n$ and energy $E_n$ of the $n$-th orbit.
For an electron in a circular orbit, the centripetal force is provided by the Coulomb electrostatic force:
Final Result
$$\boxed{r_n = \frac{n^2 h^2 \varepsilon_0}{\pi m e^2} = n^2 \times 0.53 \text{ \AA}}$$
$$\boxed{E_n = -\frac{me^4}{8\varepsilon_0^2 n^2 h^2} = -\frac{13.6}{n^2} \text{ eV}}$$
The negative sign indicates the electron is bound to the nucleus.
Examiner Tip: State all three postulates of Bohr’s model first — this itself carries marks. Clearly label equations and show all algebraic steps. Write the values of $r_1 = 0.53$ Å and $E_1 = -13.6$ eV. Mention that $r_n \propto n^2$ and $E_n \propto -1/n^2$. Note that total energy is negative (bound state) and that $KE = -E_n$ while $PE = 2E_n$. If asked for limitations, state: works only for hydrogen-like atoms, does not explain fine structure or Zeeman effect.